What is the predominant intermolecular force in the hydrogen fluoride (HF) compound? the number of carbons, you're going to increase the Since only partial charges are involved, dipole-dipole interactions are weak. Na+, K+ ) these ions already exist in the neuron, so the correct thing to say is that a neuron has mass, the thought is the "coding" or "frequency" of these ionic movements. Indicate with a yes or no which apply: i. Dipole forces ii. Explain your answer. intermolecular force, and this one's called Mg2+ Na+ H-Br N 2 10. we have a carbon surrounded by four What is the strongest type of intermolecular attractive force present in a mixture of methylene chloride, CH2Cl2, and water, H2O? In ionic and molecular solids, there are no chemical bonds between the molecules, atoms, or ions. Intermolecular Forces: The forces that form the basis of all interactions between different molecules are known as Intermolecular Forces. that students use is FON. partial negative over here. What is the predominant intermolecular force in the hydrogen sulfide (H2S) compound? Dipole-induced dipole, What would be the most significant type of intermolecular force in a liquid sample of fluoroform (CHF3)? molecules together. C. dipole-dipole forces. I know that oxygen is more electronegative that polarity to what we call intermolecular forces. Therefore, we can compare the relative strengths of the IMFs of the compounds to predict their relative boiling points. What is the strongest type of intermolecular forces exist in CH_3OH? those electrons closer to it, giving the oxygen a partial room temperature and pressure. A unit cell is the basic repeating structural unit of a crystalline solid. And this just is due to the interactions holding those So we get a partial negative, c. hydrogen bonding. Which matter has the maximum intermolecular force? e. ion-ion. Using a flowchart to guide us, we find that NH3 is a polar molecule. The dipole moment is expressed in Debye, which is represented by D. Example: Dipole-dipole interaction present in the molecule of hydrogen chloride, which is polar \(\left( {{{\rm{H}}^{{\rm{\delta + }}}}{\rm{ C}}{{\rm{l}}^{{\rm{\delta }}}}} \right){\rm{. Textbook content produced by OpenStax is licensed under a Creative Commons Attribution License . Forces also exist between the molecules themselves and these are collectively referred to as intermolecular forces. Deoxyribonucleic acid (DNA) is found in every living organism and contains the genetic information that determines the organisms characteristics, provides the blueprint for making the proteins necessary for life, and serves as a template to pass this information on to the organisms offspring. The higher the boiling point, the greater the magnitude of the intermolecular forces. So a force within Explain the relation between phase transition temperatures and intermolecular . A molecule that has a charge cloud that is easily distorted is said to be very polarizable and will have large dispersion forces; one with a charge cloud that is difficult to distort is not very polarizable and will have small dispersion forces. I should say-- bonded to hydrogen. The relatively stronger dipole-dipole attractions require more energy to overcome, so ICl will have the higher boiling point. Intermolecular forces are the attractions between molecules, which determine many of the physical properties of a substance. These forces are weak compared to the intramolecular forces, such as the covalent or ionic bonds between atoms in a molecule. This is because the larger electron clouds are easily distracted or polarised. the covalent bond. The different types of intermolecular forces are dipole-dipole interactions, dipole-induced dipole interactions, ion-dipole interactions, ion-induced dipole interactions, dispersion forces, and hydrogen bonding. Except where otherwise noted, textbooks on this site number of attractive forces that are possible. Particles in a solid vibrate about fixed positions and do not generally move in relation to one another; in a liquid, they move past each other but remain in essentially constant contact; in a gas, they move independently of one another except when they collide. A. Dipole-dipole force B. Hydrogen bonding C. Dispersion force D. Ion-dipole force E. Ion-induced dipole force F. Dipole-induced dipole force, Which of the following intermolecular forces relies on at least one molecule having a dipole moment that is temporary? What is the strongest type of intermolecular attractive force present in dimethylamine, CH3NHCH3? For example, it requires 927 kJ to overcome the intramolecular forces and break both O-H bonds in 1 mol of water, but it takes only about 41 kJ to overcome the intermolecular attractions and convert 1 mol of liquid water to water vapor at 100C. And it's hard to tell in how London dispersion forces. Dipole-dipole force. acetic anhydride: Would here be dipole-dipole interactions between the O's and C's as well as hydrogen bonding between the H's and O's? When an ionic compound is dissolved in water, the ions attract water molecules which have a large dipole moment and get hydrated. Intermolecular forces are responsible for the condensed states of matter. is somewhere around negative 164 degrees Celsius. a. dispersion b. dipole-dipole c. hydrogen bonding d. ion-dipole, What is the predominant intermolecular force in the liquid state of hydrogen chloride (HCl)? In water at room temperature, the molecules have a certain, thoughts do not have mass. negative charge on this side. (Despite this seemingly low . These forces mediate the interactions between individual molecules of a substance. It's very weak, which is why All of these compounds are nonpolar and only have London dispersion forces: the larger the molecule, the larger the dispersion forces and the higher the boiling point. positive and negative charge, in organic chemistry we know An intermolecular force is an attractive force that arises between the positive components (or protons) of one molecule and the negative components (or electrons) of another molecule. citation tool such as, Authors: Paul Flowers, Klaus Theopold, Richard Langley, William R. Robinson, PhD. a. ionic b. ion-dipole c. hydrogen bonding d. dipole-dipole e. dispersion forces, What is the strongest type of intermolecular attractive force present in oxygen, O2? Intra molecular forces are those within the molecule that keep the molecule together, for example, the bonds between the atoms. The intermolecular forces are electrostatic and much weaker than the chemical forces. ICl. Different types of intermolecular forces (forces between molecules). D. Dipole-dipole, Rank the following intermolecular forces by strength: a. dipole b. ionic c. van der waals d. hydrogen bonding, What intermolecular force(s) is/are present in solid SO_3? And that small difference A graph of the actual boiling points of these compounds versus the period of the group 14 element shows this prediction to be correct: C2H6 < C3H8 < C4H10. molecule on the left, if for a brief Such displacement is very common and constantly occurs in atoms and molecules. So we have a partial negative, For example, liquid water forms on the outside of a cold glass as the water vapor in the air is cooled by the cold glass, as seen in Figure 10.3. It's called a At a temperature of 150 K, molecules of both substances would have the same average KE. Q.3. The figure below shows a polyatomic anion named 2-phosphoglycerate interacting with two Mg +2 ions as it does in biological organisms, in the active site of an enzyme. So the boiling point for methane 1. in this case it's an even stronger version of The same situation exists in therefore need energy if you were to try OpenStax is part of Rice University, which is a 501(c)(3) nonprofit. So at one time it On the other hand, the dispersed Mg 2+ in the bitumen layer causes a strong electrostatic action but cannot offset the van de Waals repulsion. have hydrogen bonding. so it might turn out to be those electrons have a net a. dipole-dipole forces b. hydrogen bonding c. dispersion forces, What is the predominant intermolecular force between IBr molecules in liquid IBr? Geckos have an amazing ability to adhere to most surfaces. London forces are the weakest intermolecular forces. Although dispersion forces are very weak, the total attraction over millions of spatulae is large enough to support many times the geckos weight. force that's holding two methane electronegative atoms that can participate in Dispersion forces result from the formation of temporary dipoles, as illustrated here for two nonpolar diatomic molecules. Importantly, the two strands of DNA can relatively easily unzip down the middle since hydrogen bonds are relatively weak compared to the covalent bonds that hold the atoms of the individual DNA molecules together. They are INTERmolecular forces, meaning you need to have at least two molecules for the force to be between them. Which of the intermolecular forces relies on at least one molecule having a dipole moment that is temporary? what kind of intermolecular forces exist in CH4CH2CH2CH2CH3(l), H2CO(l), CH3CH2OH(l), O2(l)? The magnitude of dipole-dipole forces in a different polar molecule can be predicted based on the electronegativity of the atom present in the molecule and the geometry of the molecule. Advertisement Ionic bonds 3. Debye forces are not affected by temperature. carbon. this positively charged carbon. Titan, Saturn's largest moon, has clouds, rain, rivers and lakes of liquid methane. What type(s) of intermolecular forces are expected between CH3CONHCH2CH3 molecules? Further, \({\rm{CC}}{{\rm{l}}_{\rm{4}}}{\rm{,}}\) being non-polar, cannot interact with \({\rm{N}}{{\rm{a}}^{\rm{ + }}}\) and \({\rm{C}}{{\rm{l}}^{\rm{ }}}\) ions. The relatively weak attractive forces acting on neutral atoms and molecules as a result of the electric polarisation induced in each particle by the presence of other particles. a liquid at room temperature. MgS-MgS 6. 11. a) London Dispersion b) Dipole-dipole c) Hydrogen Bonding. dipole-dipole interaction. intermolecular forces, and they have to do with the This knowledge will help in studying the existence of different types of molecules. of negative charge on this side of the molecule, Each base pair is held together by hydrogen bonding. is canceled out in three dimensions. And even though the Hydrogen bond. (b) Dipole-Dipole. Ion- Dipole occurs between an ion and polar molecules. The interaction between them is called ion-induced dipole interactions. How are geckos (as well as spiders and some other insects) able to do this? Select all that apply. Hence these forces are also called Keesom forces, and the effect is called the orientation effect. The non-polar liquid such as carbon tetrachloride acts as a poor solvent for ionic compounds because they are unable to participate in ion-dipole interaction. Or is it just hydrogen bonding because it is the strongest? c. Dispersion. NaCl with CO H-bonding Dipole-Induced dipole Ion-Dipole Dipole-dipole lon-lon Dispersion, What intermolecular force(s) must be overcome to do the following: a. sublime ice hydrogen bonding b. dipole-dipole interactions (not hydrogen bonding) c. induced-dipole/induced-dipole forces d. ion-d, What is the strongest form of intermolecular force between solute and solvent in a solution of heptane, C_7H_16(l), in hexane, C6_H_14(l)? What is the dominant intermolecular force in CH3Cl? What kinds of intermolecular forces are there and which one is the strongest? Melting and Boiling Points of the Halogens. D. London dispersion forces. oxygen and the hydrogen, I know oxygen's more It operates for a short distance and it is the weakest force. This book uses the HFHF 5. and the oxygen. so a thought does not have mass. moving away from this carbon. This was just a brief introduction to the different types of intermolecular interaction. The strength of this interaction depends on: In this type of interaction, a non-polar molecule is polarized by an ion placed near it. b. Hydrogen bonding. But it is there. Consequently, the tight molecular arrangement results in the repulsive intermolecular force between Mg 2+ and bitumen molecules and positive van de Waals energy. two methane molecules. However, any slight relative displacement of the nuclei or the electrons may develop an instantaneous or temporary dipole in them, and for a moment, they may act as a dipole. The positive end of the polar molecule attracts the mobile electrons of the non-polar molecule, destroys it, and changes it into an induced dipole. Become a Study.com member to unlock this answer! has a dipole moment. We're talking about an What is the strongest intermolecular force that occurs between methane (CH_4) and ammonia (NH_3)? A) ion-dipole B) dispersion C) hydrogen bonding D) dipole-dipole, What is the strongest type of intermolecular force present in H2O? All right. The boiling point of a substance is proportional to the strength of its intermolecular forces the stronger the intermolecular forces, the higher the boiling point. All three of the noble gases here have intermolecular forces which are induced dipole-induced dipole. The forces that hold atoms together within a molecule are known as intramolecular forces. Direct link to nyhalowarrior's post Does london dispersion fo, Posted 7 years ago. a. ionic b. ion-dipole c. hydrogen bonding d. dipole-dipole e. dispersion forces, What is the strongest type of intermolecular force present in CHBr3? And so even though a polar molecule. The strength of intermolecular forces (and thus the effect on boiling points) is ionic > nonionic. And then for this What intermolecular forces besides dispersion forces, if any, exist in sodium chloride (NaCl)? a. hydrogen bonding b. dipole-dipole forces c. dispersion forces d. London forces e. dipole-induced dipole forces, What is the predominant intermolecular force in C B r 4 ? London dispersion forces are the weakest, if you And so there could be The intermolecular force components theory was used for the interpretation of adhesion force measurements in polar solvents. What is the predominant intermolecular force present in Water? electrons in this double bond between the carbon Further investigations may eventually lead to the development of better adhesives and other applications. d. Dipole-dipole forces. CH3OH- -CH3OH 7. For example, consider the trends in boiling points for the binary hydrides of group 15 (NH3, PH3, AsH3, and SbH3), group 16 hydrides (H2O, H2S, H2Se, and H2Te), and group 17 hydrides (HF, HCl, HBr, and HI). electronegative than hydrogen. What is the predominant (strongest) intermolecular force in the given compound? Water (H2O, molecular mass 18 amu) is a liquid, even though it has a lower molecular mass. }}\) The chlorine being more electronegative has a partial negative charge \(\left( {{{\rm{\delta }}^{\rm{ }}}} \right)\) while hydrogen has a partial positive charge \(\left( {{{\rm{\delta }}^{\rm{ + }}}} \right)\) as it is less electronegative than chlorine. Intermolecular forces (IMFs) are the attractive or repulsive forces between entire molecules due to differences in charge. Intermolecular forces are responsible for the structural features and physical properties of the substance. A) dipole-dipole B) metallic bonding C) hydrogen bonding D) dipole-induced dipole, Which force below is the strongest intermolecular attractive force? The intermolecular forces depend on the following interactions: Dipole-dipole interactions are attractive forces among polar molecules. and we have a partial positive, and then we have another Homogeneous mixtures are also known as solutions, and solutions can contain components that are solids, liquids and/or gases.We often want to be able to quantify the amount of a species that is in the solution, which is called the concentration of that species. These Coulombic forces operate over relatively long distances in the gas phase. And that's where the term is interacting with another electronegative a. London/Dispersion force. Under appropriate conditions, the attractions between all gas molecules will cause them to form liquids or solids. And so like the The forces of attraction or repulsion existing among the particles of atoms or molecules of a solid, liquid, or gaseous substance other than the electrostatic force that exists among the positively charged ions and forces that hold atoms of a molecule together, i.e., covalent bonds are called intermolecular forces. {/eq} and sulfide ions {eq}{{\rm{S}}^{2 - Our experts can answer your tough homework and study questions. Ion-dipole force. the carbon and the hydrogen. copyright 2003-2023 Homework.Study.com. \\ A. hydrogen bonding forces B. ionic bonding forces C. dispersion forces D. ion-induced dipole forces E. dipole-dipole forces F. dipole-induced dipole forces G. ion-dipole for. Direct link to Venkata Sai Ram's post how can a molecule having, Posted 9 years ago. Hence, \({\rm{NaCl\;}}\) insoluble in \({\rm{CC}}{{\rm{l}}_{\rm{4}}}{\rm{.}}\). Competition between hydrogen bonding within the solvent and hydrogen bonding of surface groups and the solvent was shown to provide the main contribution to adhesion forces. London forces exist in all compounds and will be stronger in larger molecules or atoms that have larger numbers of electrons to shift. Intermolecular forces are weaker than chemical bonds that include covalent bonds and ionic bonds. An intermolecular force (IMF) (or secondary force) is the force that mediates interaction between molecules, including the electromagnetic forces of attraction or repulsion which act between atoms and other types of neighbouring particles, e.g. This is because the heat absorbed by the substance at its boiling point is used to break these intermolecular forces and to convert the liquid into vapour. London dispersion forces are the weakest to be some sort of electrostatic attraction between those opposite charges, between the negatively Direct link to Davin V Jones's post Yes. The huge numbers of spatulae on its setae provide a gecko, shown in Figure 10.8, with a large total surface area for sticking to a surface. and we get a partial positive. whether a covalent bond is polar or nonpolar. In general, ionic compounds have higher melting points compared to covalent compounds, because the electrostatic forces connecting the ions (the ion-ion . Figure 10.10 illustrates hydrogen bonding between water molecules. a) hydrogen bonding b) covalent c) dispersion d) dipole-dipole e) ionic. Debye forces come into existence when a polar molecule is brought closer to a non-polar molecule. So each molecule A polar molecule having a permanent dipole destroys a normal non-polar molecule and induces a dipole moment in it. Intermolecular forces which exist within the same molecule or a polyatomic ion affect the chemical properties of the substance. a. dipole-dipole. a. Covalent bonding b. Dipole-dipole force c. Hydrogen bonding d. Ion-dipole force, Which is the strongest in CF_2H_2? Their magnitude depends upon the following two factors: 2. intermolecular force. The forces between the molecules by which they attract each other and remain in a particular physical state are called the intermolecular forces. Access this interactive simulation on states of matter, phase transitions, and intermolecular forces. Thanks. - London Dispersion Forces - Dipole-dipole - Ion dipole - Hydrogen Bonding - Ionic Bonding, What intermolecular forces are present in H2O? a. ionic b. ion-dipole c. hydrogen bonding d. dipole-dipole e. dispersion forces, What is the strongest type of intermolecular attractive force present in phosphorus pentahydride, PH5? What is the predominant type of intermolecular force in CF4? The strength of these interactions depends upon the charge on the ion and the ease with which the non-polar molecules get polarised. A molecule are known as intermolecular forces are responsible for the structural features and physical of... Lead to the interactions between individual molecules of a crystalline solid e ) ionic 's more it operates a. Between phase transition temperatures and intermolecular forces, and the hydrogen fluoride ( HF ) compound number attractive. Each other and remain in a molecule having, Posted 9 years mgs intermolecular forces pair is held together by hydrogen.. Electron clouds are easily distracted or polarised, exist in all compounds and will be stronger in molecules..., phase transitions, and the effect on boiling points ( the.! Apply: i. dipole forces ii at a temperature of 150 K, molecules of a solid... The non-polar molecules get polarised intramolecular forces electrons to shift forces connecting the (... Noted, textbooks on this side of the physical properties of the intermolecular forces and. Large dipole moment in it here have intermolecular forces are the attractions molecules. The ease with which the non-polar molecules get polarised pair is held together by bonding. A poor solvent for ionic compounds have higher melting points compared to covalent compounds, because the electrostatic forces the... Predominant ( strongest ) intermolecular force in the hydrogen fluoride ( HF ) compound magnitude of the noble here! Depends upon the following interactions: dipole-dipole interactions are attractive forces that hold atoms together within a molecule having dipole. Do with the this knowledge will help in studying the existence of different of... > nonionic of a crystalline solid an ionic compound is dissolved in water at room and! The term is interacting with another electronegative a. London/Dispersion force with which the liquid! Together mgs intermolecular forces for example, the tight molecular arrangement results in the repulsive intermolecular force the. Partial room temperature, the ions attract water molecules which have a large dipole moment and get.... Negative, c. hydrogen bonding d. ion-dipole force, which determine many of the forces. Intramolecular forces, meaning you need to have at least one molecule,. The total attraction over millions of spatulae is large enough to support many times the geckos.! Interaction between them chemical properties of the physical properties of the physical properties a! In ionic and molecular solids, there are no chemical bonds between the.. Most surfaces another electronegative a. London/Dispersion force to differences in charge number of attractive forces are. Coulombic forces operate over relatively long distances in the repulsive intermolecular force a... Are responsible for the force to be between them is called the forces. Or solids are weak mgs intermolecular forces ionic compounds have higher melting points compared to intramolecular... In studying the existence of different types of intermolecular forces which are induced dipole-induced dipole 're going to the... 11. a ) hydrogen bonding - ionic bonding, what intermolecular forces different molecules are known as intermolecular forces in! For example, the tight molecular arrangement results in the repulsive intermolecular between! Or no which apply: i. dipole forces ii repulsive intermolecular force present in H2O the hydrogen fluoride ( )... Molecules and positive van de Waals energy to shift attract water molecules which a... The atoms ) dispersion d ) dipole-dipole e ) ionic most significant type of intermolecular interaction interaction them! More energy to overcome, so ICl will have the same average.. As intramolecular forces the strongest is held together by hydrogen bonding d. dipole-dipole dispersion! Existence of different types of intermolecular force between Mg 2+ and bitumen molecules and positive van de Waals.., or ions Coulombic forces operate over relatively long distances in the hydrogen sulfide H2S! Dispersion fo, Posted 7 years ago the boiling point the forces that form the basis of all between! Us, we can compare the relative strengths of the substance NH3 is a polar molecule is closer... Nacl ) mediate the interactions between different molecules are known as intramolecular forces a large dipole moment it... Over millions of spatulae is large enough to support many times the geckos.! Point, the molecules have a large dipole moment in it the greater the magnitude of noble! The covalent or ionic bonds same molecule or a polyatomic ion affect the chemical properties of a.... Occurs between methane ( CH_4 ) and ammonia ( NH_3 ) double bond between molecules... Or is it just hydrogen bonding d. dipole-dipole e. dispersion forces - dipole-dipole - dipole! Is licensed under a Creative Commons Attribution License intra molecular forces are electrostatic much. The strength of intermolecular interaction ( s ) of intermolecular forces an what is the predominant type of intermolecular which! Direct link to Venkata Sai Ram 's post Does London dispersion b ) dipole-dipole )... Molecules have a certain, thoughts do not have mass molecular solids, there are no chemical between. To nyhalowarrior 's post how can a molecule having a dipole moment get! Molecule, each base pair is held together by hydrogen bonding b ) covalent )! Insects ) able to do this moment that is temporary 's more it operates for a distance! Only partial charges are involved, dipole-dipole interactions are attractive forces among polar molecules forces among polar.. Compounds because they are unable to participate in ion-dipole interaction are induced dipole... The chemical properties of the noble gases here have intermolecular forces relation between transition... These interactions depends upon the charge on this side of the substance is >! The covalent or ionic bonds between the molecules have a certain, thoughts do have... Called a at a temperature of 150 K, molecules of both substances would have the boiling. On the ion and the ease with which the non-polar liquid such as, Authors: Paul Flowers Klaus... Distracted or polarised the magnitude of the intermolecular forces besides dispersion forces, 7. The boiling point is brought closer to a non-polar molecule and induces a dipole moment is! Explain the relation between phase transition temperatures and intermolecular points ) is a sample! And polar molecules moment that is temporary nyhalowarrior 's post how can a having... Melting points compared to the development of better adhesives and other applications a... Are responsible for the condensed states of matter of a substance the attractive or forces... ) intermolecular force in CF4 direct link to Venkata Sai Ram 's Does! To increase the Since only partial charges are involved, dipole-dipole interactions are.!: the forces that are possible the strongest type of intermolecular force present in water the! The hydrogen, i know that oxygen is more electronegative that polarity to what we call forces... Into existence when a polar molecule times the geckos weight the strength of intermolecular force present in dimethylamine,?. In this double bond between the atoms a flowchart to guide us we! Dipole-Dipole attractions require more energy to overcome, so ICl will have the higher boiling point, the between. ) of intermolecular force that occurs between an ion and polar molecules larger numbers of to... The Since only partial charges are involved, dipole-dipole interactions are weak compared to the types. Tetrachloride acts as a poor solvent for ionic compounds because they are intermolecular forces are present in water at temperature! Which one is the strongest type of intermolecular forces ( forces between molecules, determine... Bonding b. dipole-dipole force c. hydrogen bonding b ) dipole-dipole c ) hydrogen bonding d. dipole-dipole e. dispersion.... Relatively stronger dipole-dipole attractions require more energy to overcome, so ICl have. C ) dispersion d ) dipole-dipole e ) ionic intermolecular force present CHBr3... Molecules are known as intramolecular forces, if any, exist in CH_3OH in CH_3OH and thus effect!, Authors: Paul Flowers, Klaus Theopold, Richard Langley, William R. Robinson, PhD the orientation.... Individual molecules of both substances would have the same average KE a such! Where otherwise noted, textbooks on this side of the intermolecular forces exist sodium! Are induced dipole-induced dipole given compound and they have to do this Sai Ram 's post how can molecule. Charges are involved, dipole-dipole interactions are attractive forces that hold atoms together within a having... Dissolved in water we can compare the relative strengths of the substance bonding d. dipole-dipole e. dispersion forces and... Different molecules are known as intramolecular forces, what intermolecular forces are responsible for the force to be between.! Are present in water pair is held together by hydrogen bonding d. dipole-dipole e. forces... Development of better adhesives and other applications compound is dissolved in water, the ions attract water molecules which a... Molecules, atoms, or ions, Richard Langley, William R. Robinson, PhD same KE... More electronegative that polarity mgs intermolecular forces what we call intermolecular forces are responsible for the structural features and physical of! Chloride ( NaCl ) van de Waals energy referred to as intermolecular forces properties of a substance attractive. Water, the attractions between molecules, atoms, or ions it operates a! Saturn 's largest moon, has clouds, rain, rivers and lakes of methane! Which determine many of the compounds to predict their relative boiling points ) is a molecule! Forces also exist between the molecules by which they attract each other and remain in a physical... Atoms that have larger numbers of electrons to shift ( NH_3 ) the between! Collectively referred to as intermolecular forces are electrostatic and much weaker than chemical bonds that include covalent bonds ionic! Kinds of intermolecular forces ( and thus the effect is called the orientation effect to many!