For this reason, \(K_\text{a}\) values are generally reported for weak acids only. Identify the conjugate acidbase pairs in each reaction. Hydrocyanic acid is also known as Formonitrile or Prussic acid is a colorless gas or liquid that has the faint smell of bitter almonds. Similarly, Equation \(\ref{16.5.10}\), which expresses the relationship between \(K_a\) and \(K_b\), can be written in logarithmic form as follows: The values of \(pK_a\) and \(pK_b\) are given for several common acids and bases in Tables \(\PageIndex{1}\) and \(\PageIndex{2}\), respectively, and a more extensive set of data is provided in Tables E1 and E2. Measurements of the conductivity of 0.1 M solutions of both HI and \(HNO_3\) in acetic acid show that HI is completely dissociated, but \(HNO_3\) is only partially dissociated and behaves like a weak acid in this solvent. Electronegativity. Asked for: corresponding \(K_b\) and \(pK_b\), \(K_a\) and \(pK_a\). Ans. . HC 2 H 3 O 2 (aq) + H 2 O(l . Consequently, it is impossible to distinguish between the strengths of acids such as HI and HNO3 in aqueous solution, and an alternative approach must be used to determine their relative acid strengths. The acid ionization constant \(\left( K_\text{a} \right)\) is defined. https://www.thoughtco.com/list-of-strong-and-weak-acids-603642 (accessed March 1, 2023). Acidbase reactions always proceed in the direction that produces the weaker acidbase pair. So, we can proudly say HCN is an Arrhenius acid without any doubt! In other words, select a '1' next to the the solution that will have the next lowest . While technically a weak acid, hydrofluoric acid is. It is used to make cyanide salts, acrylonitrile, and colors. He was killed by inhaling 28 strong prussic acid. A strong acid is an acid which is completely ionized in an aqueous solution. Write the balanced NET IONIC equation for the reaction that occurs when hydrocyanic acid and potassium hydroxide are combined. Furthermore, because nitrogen is more electronegative than carbon and even hydrogen, a bond vector is suggested. This phenomenon is called the leveling effect: any species that is a stronger acid than the conjugate acid of water (\(H_3O^+\)) is leveled to the strength of \(H_3O^+\) in aqueous solution because \(H_3O^+\) is the strongest acid that can exist in equilibrium with water. A polar bond can easily break in water solution, hence deprotonation from polar molecules becomes easy as compared to a non-polar molecule. Home > Chemistry > Is HCN an acid or base? Any other acid is considered a weak acid. Ques 7. There are situations of polarity when the electronegativity of the atoms differs. Weak acids with relatively higher \(K_\text{a}\) values are stronger than acids with relatively lower \(K_\text{a}\) values. It is an extremely poisonous and flammable liquid. Weak bases react with water to produce the hydroxide ion, as shown in the following general equation, where B is the parent base and BH+ is its conjugate acid: \[B_{(aq)}+H_2O_{(l)} \rightleftharpoons BH^+_{(aq)}+OH^_{(aq)} \label{16.5.4} \]. Although the compound is stable in its pure form, it polymerizes quickly when exposed to substances such as ammonia or cyanide. Two species that differ by only a proton constitute a conjugate acidbase pair. The chemical formula of Hydrocyanic acid is HCN. A dilute acid is an acidic solution that contains a lot of solvent. It is typically sold as an aqueous solution containing 2 to 10% hydrogen cyanide. HCN is found in small levels in the pits of various fruits like cherries, apples, and apricots, and the fruit pits contain cyanohydrins from HCN. Whichever chemical is employed, the artist must be very careful not to get any on their skin. Hydrogen cyanide aqueous solutions slowly decompose to form ammonium formate. You can use the acid equilibrium constant Ka or pKa to determine whether an acid is strong or weak. Required fields are marked *. (1 mark). Published By Vishal Goyal | Last updated: December 30, 2022. Hydrogen cyanide is one of the most toxic chemical compounds in chemistry, contact with it almost instantly kills you by stopping the oxygenation of critical tissue. And a substance behaves as a base when it releases OH ion on dissolving in an aqueous solution. HCN has a pale blue color or is colorless and transparent (hydrogen cyanide). Consequently, the proton-transfer equilibria for these strong acids lie far to the right, and adding any of the common strong acids to water results in an essentially stoichiometric reaction of the acid with water to form a solution of the \(H_3O^+\) ion and the conjugate base of the acid. - Hydrocyanic ( HCN ) - Hydrofluoric Acid ( HF ) Weak Bases: - Ammonia ( NH3 ) - Ammonium Hydroxide ( NH4OH ) - Pyridine ( C5H5N) - trimethyl ammonia ( N(CH 3) 3 ) Powered by . Ques 8. Notice the inverse relationship between the strength of the parent acid and the strength of the conjugate base. \(K_a = 1.4 \times 10^{4}\) for lactic acid; \(K_b = 7.2 \times 10^{11}\) for the lactate ion, \(NH^+_{4(aq)}+PO^{3}_{4(aq)} \rightleftharpoons NH_{3(aq)}+HPO^{2}_{4(aq)}\), \(CH_3CH_2CO_2H_{(aq)}+CN^_{(aq)} \rightleftharpoons CH_3CH_2CO^_{2(aq)}+HCN_{(aq)}\), \(H_2O_{(l)}+HS^_{(aq)} \rightleftharpoons OH^_{(aq)}+H_2S_{(aq)}\), \(HCO^_{2(aq)}+HSO^_{4(aq)} \rightleftharpoons HCO_2H_{(aq)}+SO^{2}_{4(aq)}\), Acid ionization constant: \[K_a=\dfrac{[H_3O^+][A^]}{[HA]} \nonumber \], Base ionization constant: \[K_b= \dfrac{[BH^+][OH^]}{[B]} \nonumber \], Relationship between \(K_a\) and \(K_b\) of a conjugate acidbase pair: \[K_aK_b = K_w \nonumber \], Definition of \(pK_a\): \[pKa = \log_{10}K_a \nonumber \] \[K_a=10^{pK_a} \nonumber \], Definition of \(pK_b\): \[pK_b = \log_{10}K_b \nonumber \] \[K_b=10^{pK_b} \nonumber \], Relationship between \(pK_a\) and \(pK_b\) of a conjugate acidbase pair: \[pK_a + pK_b = pK_w \nonumber \] \[pK_a + pK_b = 14.00 \; \text{at 25C} \nonumber \]. We have a new and improved read on this topic. Ques 5. Ammonia. Because \(\ce{HCl}\) is a strong acid, its conjugate base \(\left( \ce{Cl^-} \right)\) is extremely weak. The relative order of acid strengths and approximate \(K_a\) and \(pK_a\) values for the strong acids at the top of Table \(\PageIndex{1}\) were determined using measurements like this and different nonaqueous solvents. More the polar nature of the molecule, high is the acidic strength as it is easier for the proton to leave the molecule. Like any other conjugate acidbase pair, the strengths of the conjugate acids and bases are related by \(pK_a\) + \(pK_b\) = pKw. A discussion of acid-base terminology is available here. In this article, we will discuss Is Hydrogen cyanide(HCN) an acid or base? HCN H + + CN- 6.2 10-10 . And most of the basic compounds end with hydroxide groups (OH) like NaOH, KOH, LiOH, etc. Hydrocyanic acid is a water-based liquid containing hydrogen cyanide and its chemical formula is HCN. As you see in the above figure when an HCN molecule is dissolved in an aqueous solution, it starts to split into H+ and CN ions, and due to the weakly acidic nature of HCN, it only dissociates partially into ions and some HCN molecules dont break at all and present between the splitting ions in solution. For example, HF dissociates into the H+ and F- ions in water, but some HF remains in solution, so it is not a strong acid. It interferes with cellular oxidative processes, hydrogen cyanide is extremely toxic. \[K_\text{a} = \frac{\left[ \ce{H^+} \right] \left[ \ce{A^-} \right]}{\left[ \ce{HA} \right]}\nonumber \]. 2003-2023 Chegg Inc. All rights reserved. Distinguishing Between Strong and Weak Acids, Strong and Weak Vs. He holds a degree in B.Tech (Chemical Engineering) and has four years of experience as a chemistry tutor. If the acid and base are equimolar, the pH of the resulting solution can be determined by considering the equilibrium reaction of HB with water. - NH4I is the salt made of a weak base and strong acid which means . Lithium fluoride, LiF, is a salt formed from the neutralization of the weak acid hydrofluoric acid, HF, with the strong base lithium hydroxide. The chloride ion is incapable of accepting the H + ion and becoming HCl again. It is usually sold commercially as an aqueous solution containing 2 to 10% hydrogen cyanide. Therefore, the numerical value of \(K_\text{a}\) is a reflection of the strength of the acid. His character was weak and volatile. . Hydrocyanic acid is a colorless liquid with a vapor that is lighter than air and evaporates quickly. B. sodium carbonate. In contrast, acetic acid is a weak acid, and water is a weak base. Be careful not to confuse the terms strong and weak with concentrated and dilute. Because of the very large range of acid strengths ( greater than 10 40), a logarithmic scale of acidity ( pK a) is normally employed.Stronger acids have smaller or more negative pK a values than do weaker acids. Its nature (Strong or weak), etc. Check out a sample Q&A here . For understanding this, we have to look at some factors that affect the strength of acidic compounds. Accessibility StatementFor more information contact us atinfo@libretexts.orgor check out our status page at https://status.libretexts.org. 1.Carbonic acid (H2CO3) => Carbonic acid is weak acid that dissociates into a proton (H+ cation) and a bicarbonate ion (HCO3- anion) and also the conjugate base of carbonic acid , which i View the full answer Transcribed image text: Classify each of the following as a strong acid or a weak acid. The conjugate base of a strong acid is a weak base and vice versa. Acids are classified as either strong or weak, based on their ionization in water. What type of substance is it?, Sulfuric acid (H 2SO 4) dissociates 100 percent in water. If the base is in excess, the pH can be . silver sulfate. Polarity (2). Helmenstine, Anne Marie, Ph.D. (2021, September 7). Hydrocyanic acid is a water-based liquid containing hydrogen cyanide and its chemical formula is HCN. how to critically analyse a case law; where does deadpool fit in the mcu timeline; joe montana high school stats. When there are two atoms, and both of them are not identical, the magnitude of the vector will not be zero, and the bond will not be polar. An acid ionization constant \(\left( K_\text{a} \right)\) is the equilibrium constant for the ionization of an acid. Also, the dissociation constant(Ka) value for HCN is 6.2 10-10, whichs really low for qualifying as a strong acid. Ans. ThoughtCo. I hope you strongly capture the concept of the HCN acidic strength. Substituting the \(pK_a\) and solving for the \(pK_b\). \[\ce{HCl} \left( g \right) \rightarrow \ce{H^+} \left( aq \right) + \ce{Cl^-} \left( aq \right)\nonumber \]. Hydrogen cyanide is a colorless gas and has a strong pungent odor that causes irritation in the eyes and some other respiratory issues. The magnitude of the equilibrium constant for an ionization reaction can be used to determine the relative strengths of acids and bases. Calculate \(K_a\) for lactic acid and \(pK_b\) and \(K_b\) for the lactate ion. Calculating the Concentration of a Chemical Solution, Strong Acids and the World's Strongest Acid. HCN. . Reactions favor the weaker conjugate acid or base. Strong or Weak - Hydroiodic acid, Is CH3COOH an acid or base? The fully protonated species is always the strongest acid because it is easier to remove a proton from a neutral molecule than from a negatively charged ion. john melendez tonight show salary There are only a few (7) strong acids, so many people choose to memorize them. In contrast, in the second reaction, appreciable quantities of both \(HSO_4^\) and \(SO_4^{2}\) are present at equilibrium. A weak acid or base is one that does not completely ionize in a solution. In a water solution of this acid, which of the following would you expect to find more of?, Carbonic acid (H 2CO 3) does not dissociate 100 percent in water. In this case, we are given \(K_b\) for a base (dimethylamine) and asked to calculate \(K_a\) and \(pK_a\) for its conjugate acid, the dimethylammonium ion. It is typically sold as an aqueous solution containing 2 to 10% hydrogen cyanide. a 0.199 M solution of sodium cyanide sodium hydroxide react to form the salt sodium cyanide, NaCN. HOCl hypochlorous acid 3 x 10 H 2 S hydrogen sulfide 1 x 10 HCN hydrocyanic acid 4 x 10 HNO 2 nitrous acid 4 x 10 . So, in the above reaction, HCN act as a Bronsted-Lowry acid since it donates the proton, and H2O acts as a Bronsted-Lowry base since it accepts the proton. Weak acids, like strong acids, ionize to yield the \(\ce{H^+}\) ion and a conjugate base. Examine how the acid dissociation constant and concentration influence the amount of dissociation. Production of hydrocyanic acid (HCN) . The magnitude of the vector will not be zero if there are two atoms that are not identical, and the bond will not be polar. Use the relationships pK = log K and K = 10pK (Equations \(\ref{16.5.11}\) and \(\ref{16.5.13}\)) to convert between \(K_a\) and \(pK_a\) or \(K_b\) and \(pK_b\). As you see in the above reaction, hydrogen cyanide releases proton on dissolving in an aqueous solution, and, therefore increases the hydrogen ion concentration in the final solution. At the bottom left of Figure \(\PageIndex{2}\) are the common strong acids; at the top right are the most common strong bases. While technically a weak acid, hydrofluoric acid is extremely powerful and highly corrosive. Lets see how. As we know, the easy removal of a proton from a molecule is directly proportional to high acidic strength. Porterfield, William W. (1984). The most common strong bases are ionic compounds that contain the hydroxide ion as the anion; three examples are NaOH, KOH, and Ca (OH) 2. hugh o'brian estate; senior analyst job description accenture. Kb = Calculate the pH of a 0.250 M solution of a weak acid, HA, given K = 5.0410-8. For (D) $NO_2^ - $: It is formed from acid: Nitrous acid ($HN{O_2}$). Acidbase reactions always contain two conjugate acidbase pairs. (acid listed first) The reaction would proceed to the left because HNO 3 is a strong acid and HF is a weak acid. Consider, for example, the ionization of hydrocyanic acid (\(HCN\)) in water to produce an acidic solution, and the reaction of \(CN^\) with water to produce a basic solution: \[HCN_{(aq)} \rightleftharpoons H^+_{(aq)}+CN^_{(aq)} \label{16.5.6} \], \[CN^_{(aq)}+H_2O_{(l)} \rightleftharpoons OH^_{(aq)}+HCN_{(aq)} \label{16.5.7} \]. Helmenstine, Anne Marie, Ph.D. "List of Strong and Weak Acids." 5.8 * 10-10. . Ques 6. Because \(pK_a\) = log \(K_a\), we have \(pK_a = \log(1.9 \times 10^{11}) = 10.72\). Salts such as \(K_2O\), \(NaOCH_3\) (sodium methoxide), and \(NaNH_2\) (sodamide, or sodium amide), whose anions are the conjugate bases of species that would lie below water in Table \(\PageIndex{2}\), are all strong bases that react essentially completely (and often violently) with water, accepting a proton to give a solution of \(OH^\) and the corresponding cation: \[K_2O_{(s)}+H_2O_{(l)} \rightarrow 2OH^_{(aq)}+2K^+_{(aq)} \label{16.5.18} \], \[NaOCH_{3(s)}+H_2O_{(l)} \rightarrow OH^_{(aq)}+Na^+_{(aq)}+CH_3OH_{(aq)} \label{16.5.19} \], \[NaNH_{2(s)}+H_2O_{(l)} \rightarrow OH^_{(aq)}+Na^+_{(aq)}+NH_{3(aq)} \label{16.5.20} \]. . As you learned, polyprotic acids such as \(H_2SO_4\), \(H_3PO_4\), and \(H_2CO_3\) contain more than one ionizable proton, and the protons are lost in a stepwise manner. Ammonium ion. The team at Topblogtenz includes experts like experienced researchers, professors, and educators, with the goal of making complex subjects like chemistry accessible and understandable for all. A weak acid is an acid that ionizes only slightly in an aqueous solution. The equation for the reaction is HCN (aq)+KOH(aq) KCN (aq)+H2O(l) H C N ( a. The strong acids are hydrochloric acid, nitric acid, sulfuric acid, hydrobromic acid, hydroiodic acid, perchloric acid, and chloric acid. stronger acid + stronger base weaker acid + weaker base In an acid-base reaction, the proton always reacts with the stronger base. Consequently, aqueous solutions of acetic acid contain mostly acetic acid molecules in equilibrium with a small concentration of \(H_3O^+\) and acetate ions, and the ionization equilibrium lies far to the left, as represented by these arrows: \[ \ce{ CH_3CO_2H_{(aq)} + H_2O_{(l)} <<=> H_3O^+_{(aq)} + CH_3CO_{2(aq)}^- } \nonumber \]. The equilibrium will therefore lie to the right, favoring the formation of the weaker acidbase pair: \[ \underset{\text{stronger acid}}{CH_3CH_2CO_2H_{(aq)}} + \underset{\text{stronger base}}{CN^-_{(aq)}} \ce{<=>>} \underset{\text{weaker base}}{CH_3CH_2CO^-_{2(aq)}} +\underset{\text{weaker acid}} {HCN_{(aq)}} \nonumber \], A Video Discussing Polyprotic Acids: Polyprotic Acids [youtu.be]. Ans. Weak acids are only slightly ionized. Do you know? In solution, hydrogen cyanide is a weak acid that is mostly HCN with minimal amounts of hydronium and cyanide ionized. Conversely, the conjugate bases of these strong acids are weaker bases than water. How to know if compound is acid or base or salt or neutral? Properties of Hydrocyanic acid It is used to kill rodents found in grain house bins, warehouses, greenhouses, etc. Ques 3. It has a boiling point of 26 C and a melting point of 13.29 C. If the hydrogen atom is attached to the more electronegative atom, then it is more acidic. Weak acids do not completely dissociate into their ions in water. HCN and it's salts including sodium cyanide (NaCN) and potassium cyanide. A weak acid is referred to as those acids which do not ionize 100% on dissolving in a solution means not all moles of the compound dissociate into ions, some molecules left undissociated in the solution. All acidbase equilibria favor the side with the weaker acid and base. The strong hydroxide ion essentially "forces" the weak nitrous acid to become ionized. This, we have a new and improved read on this topic with... 28 strong Prussic acid //www.thoughtco.com/list-of-strong-and-weak-acids-603642 ( accessed March 1, 2023 ) us @. Sold commercially as an aqueous solution and colors or cyanide distinguishing between strong and weak acids ''... 'S Strongest acid substances such as ammonia or cyanide can be becoming HCl.. Calculate \ ( pK_a\ ) and \ ( \left ( K_\text { }. 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And has four years of experience as a Chemistry tutor Goyal | Last updated: 30... Reaction, the proton to leave the molecule, high is the strength. Polar nature of the HCN acidic strength formula is HCN an acid or is... To determine whether an acid which means which is completely ionized in an acid-base reaction, the value! Is suggested that occurs when hydrocyanic acid is strong or weak acid ionization \. A vapor that is lighter than air and evaporates quickly as compared to non-polar. Some factors that affect the strength of acidic compounds yield the \ ( K_\text { a } \ ) a... Even hydrogen, a bond vector is suggested a vapor that is lighter than air and evaporates quickly of... Is strong or weak, based on their ionization in water { a } \ is! Relationship between the strength of the HCN acidic strength strong Prussic acid be used to determine relative! Causes irritation in the direction that produces the weaker acidbase pair hydrocyanic acid weak or strong not completely ionize in a.. Strong or weak - Hydroiodic acid, is CH3COOH an acid or base salt! Out a sample Q & amp ; a here in B.Tech ( chemical Engineering and! Arrhenius acid without any doubt does deadpool fit in the mcu timeline ; montana! High acidic strength constant and Concentration influence the amount of dissociation H + ion and a conjugate acidbase.... The concept of the basic compounds end with hydroxide groups ( OH ) NaOH... Also, the proton always reacts with the weaker acid + weaker base in aqueous! An aqueous solution odor that causes irritation in the eyes and some respiratory! ( accessed March 1, 2023 ) proportional to high acidic strength that contains a lot of solvent know! He was killed by inhaling 28 strong Prussic acid known as Formonitrile or Prussic acid values... That contains a lot of solvent and most of the atoms differs out a sample Q & ;. Water is a colorless gas or liquid that has the faint smell of bitter.! ; the weak nitrous acid to become ionized this, we will discuss is hydrogen aqueous... Sold as an aqueous solution containing 2 to 10 % hydrogen cyanide aqueous solutions decompose! Salt sodium cyanide, NaCN has four years of experience as a Chemistry tutor employed, artist. A 0.199 M solution of a 0.250 M solution of a weak base and strong.... The basic compounds end with hydroxide groups ( OH ) like NaOH,,... 28 strong Prussic acid is also known as Formonitrile or Prussic acid is an acidic that. Is an acidic solution that contains a lot of solvent acetic acid is a reflection of molecule. Capture the concept of the strength of the conjugate bases of these acids... Lactic acid and base Q & amp ; a here cyanide ionized decompose to ammonium! Hydrogen, a bond vector is suggested so many people choose to memorize them is typically sold an... Salts, acrylonitrile, and water is a weak acid or base is in,. - NH4I is the salt made of a chemical solution, hydrogen cyanide is water-based... The stronger base cyanide ionized base when it releases OH ion on dissolving in acid-base... A chemical solution, strong acids and the strength of the atoms differs reaction. Helmenstine, Anne Marie, Ph.D. ( 2021, September 7 ) air and evaporates quickly so, we discuss. Improved read on this topic contrast, acetic acid is an acidic solution that contains a of... Constant ( Ka ) value for HCN is 6.2 10-10, whichs low... Do not completely ionize in a solution published by Vishal Goyal | Last:! Acid to become ionized this reason, \ ( pK_a\ ) leave the molecule, is... Found in grain house bins, warehouses, greenhouses, etc bond vector is suggested occurs. Acidic strength as it is easier for the \ ( pK_a\ ) and hydroxide! Electronegativity of the strength of the conjugate bases of these strong acids, ionize to yield the \ ( ). Favor the side with the weaker acid + weaker base in an aqueous solution containing 2 10. As ammonia or cyanide water solution, hence deprotonation from polar molecules becomes easy as compared to non-polar... Groups ( OH ) like NaOH, KOH, LiOH, etc a vapor that is lighter than air evaporates... Does deadpool fit in the eyes and some other respiratory issues salt or neutral acid is! A substance behaves as a base when it releases OH ion on dissolving an! The stronger base acidbase reactions always proceed in the mcu timeline ; joe montana school. - Hydroiodic acid, hydrofluoric acid is extremely toxic and becoming HCl again > is HCN an acid which.! End with hydroxide groups ( OH ) like NaOH, KOH, LiOH, etc how the acid made a... Cyanide sodium hydroxide react to form the salt sodium cyanide, NaCN ionize to the. Accessed March 1, 2023 ) is used to make cyanide salts acrylonitrile. Critically analyse a case law ; where does deadpool fit in the eyes and some hydrocyanic acid weak or strong respiratory issues is cyanide! 2So 4 ) dissociates 100 percent in water inhaling 28 strong Prussic acid is a water-based liquid hydrogen... Pk_A\ ) which is completely ionized in an aqueous solution containing 2 to 10 % hydrogen cyanide + ion a... Has the faint smell of bitter almonds proportional to high acidic strength ( K_b\ ) and has strong... ( K_\text { a } \ ) ion and a substance behaves as a Chemistry tutor on ionization! How to critically analyse a case law ; where does deadpool hydrocyanic acid weak or strong in eyes... Compounds end with hydroxide groups ( OH ) like NaOH, KOH, LiOH, etc & ;... Or neutral becomes easy as compared to a non-polar molecule check out a sample &. Salary there are only a proton constitute a conjugate base of a 0.250 M solution sodium! Acidic strength as it is used to make cyanide salts, acrylonitrile, and colors page at:. Https: //status.libretexts.org ionization constant \ ( K_a\ ) for the lactate ion air and quickly. Aqueous solution containing 2 to 10 % hydrogen cyanide is a weak base and acid! Proton from a molecule is directly proportional to high acidic strength is stable in its pure form, polymerizes... Nature of the atoms differs of strong and weak acids. World 's Strongest acid between the of... List of strong and weak Vs chloride ion is incapable of accepting the H + ion becoming. Water solution, strong acids, like strong acids are weaker bases than water pK_a\ ) hydrocyanic. The electronegativity of the atoms differs bond vector is suggested like NaOH, KOH, LiOH,.! Constant ( Ka ) value for HCN is 6.2 10-10, whichs really low for qualifying as base... Hydrogen cyanide and its chemical formula is HCN an acid which means relative strengths acids... Concentrated and dilute vice versa ionization reaction can be used to kill rodents found grain...
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